| Materials and Manufacturing |
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DC-PECVD system in action. DC plasma (violet) improves the growth conditions for carbon nanotubes in this chemical vapor deposition chamber. A heating element (red) provides the necessary substrate temperature. |
Materials and manufacturing deal with the application of knowledge relating to composition, structure and processing of materials to their properties and applications.
In the last few years there was significant increase in the development of composite materials with excellent properties. Composite materials are engineered materials which are made from two or more constituent materials with significantly different physical or chemical properties. Nanotechnology has emerged as a key technology used in fabrication of composite materials.
Though "top-down" fabrication methods are still used, nanotechnology has empowered a "bottom-up" approach to modify the material properties at nanoscale level.
A classic ("top down") method for nanofabrication is electron beam lithography (EBL). In EBL a beam of electrons is scanning across a surface covered with a film (called the resist). The beam removes selectively either exposed or non-exposed regions of the resist. The result is very small structures in the resist that can be transferred into another material, for example for the creation of very small electronic devices. EBL can produce structures smaller than 10 nm which can be used in applications such as solar cells and other semiconductor and optoelectronics devices.
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Transmission electron microscopy of nanodiamond. |
An interesting method of forming a periodic nanostructure from the bottom up is called self-assembly. Self-assembly occurs when certain material are energetically attracted to one another and come together to form a repeating pattern on the molecular level. This technique has been likened to a jigsaw puzzle shaken in a box, and when the box is opened, the puzzle has assembled itself.
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Single-walled carbon nanotubes. |
Carbon nanotubes were first synthesized by the Japanese physicist Sumio Iijima when studying the deposits left on the cathode during the arc-evaporation synthesis of fullerenes (a type of carbon molecules). Since this discovery, carbon nanotubes have been synthesized by controlling the conditions of the arc-evaporation process. Aside from this synthesis method, carbon nanotubes can be fabricated using techniques such as sputtering, chemical vapor deposition, and plasma enhanced chemical vapor deposition.
